Showing posts with label Chemistry. Show all posts
Showing posts with label Chemistry. Show all posts

25 Nov 2011

New Hydrogen Storage Material Based on Liquid Nitrogen developed

Hydrogen releases in the presence of iron chloride
In a research funded by the US Department of Energy, four scientists from the University of Oregon have developed a material to store hydrogen, using boron-nitrogen-based liquid-phase.This new material has displayed stability in both air and moisture. To be more specific, the research team developed a platform based on cyclic amine borane, which is also called BN-methylcyclopentane. Apart from being stable, the platform displayed the ability to retain hydrogen without changing phase. For the purpose of hydrogen desorption, the platform used iron chloride which enabled the conversion of the used fuel into the charged state.
This is a welcome change from the current storage materials which are solid, as liquid materials allow for a smooth transition from gasoline phase to hydrogen phase. During the course of the study, the researchers initially discovered six cyclic amine borane materials that were membered. On the release of hydrogen, these materials produced a large molecule. Although these materials were in their solid state, scientists altered the structure of the materials to convert them into liquid forms. The materials that were changed into liquid form in such a manner had low vapour pressure and retained their liquid form even upon the release of hydrogen.
Scientists believe that the new platform could be applicable in devices that use fuel cells. However, they also believe that the greatest hurdle in the commercial usage of such a platform would be the increase of hydrogen yield and the development of an effective mechanism to regenerate. The US Department of Energy is encouraging research to develop a solid or liquid hydrogen fuel carrier by 2017.
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16 Nov 2011

Sweet Spot for Life's Chemistry Discovered

Astronomers home in on places ripe for formation of complex organic molecules.
Some young stars have been found to be cranking out the production of methanol, an chemical that could support life's chemistry. NASA
When scientists realized early Earth didn't have the right ingredients for life on its own, they started looking in space for the complex organic molecules needed to get things going.

Of particular interest is methanol, which can trigger the more complex chemistry that leads to amino acids, the building blocks for proteins and life.

"Methanol is the most complex molecule you can form at the really low temperatures in interstellar space," astronomer Douglas Whittet, with Rensselaer Polytechnic Institute, told Discovery News. "When you put methanol into a newly forming star system, you have some heat from a proto-sun and that's when methanol really takes off. It's the springboard for more exciting chemistry that follows."

In other words, find the methanol and scientists believe you find the chemical pathways to life.

"Searching for methanol in various regions in space will tell researchers where to look for other complex organic molecules, which will eventually lead to the formation of life," astronomer Sachindev Shenoy, with NASA's Ames Research Center in California, told Discovery News.

But where to look?
A new analysis by Whittet and colleagues shows there is a "sweet spot" around a few young stars where methanol production is cranking. What seems to be key is how fast molecules can reach dust grains, which serve as a scaffolding of sorts for chemical reactions.

"The rate of molecule accumulation on the particles can result in an organic boom or a literal dead end," Whittet said.

Not all young stars are suited for organic chemistry. Whittet's team found a range of methanol concentrations in clouds from practically zero to about 30 percent.

If molecules build up too quickly on the surfaces of dust grains, there's not enough time for chemical reactions to occur before they are buried by other molecules. If the buildup is too slow, there are fewer chances for chemical reactions.

The research has implications for understanding where to look for life and suggests it may be more plentiful, from a chemistry point of view, than previously thought.

"The clouds we're observing appear to harbor more favorable conditions for life than the pre-solar cloud from which our solar system formed. And there is life in our solar system," Amanda Cook, a post-doctoral research fellow at NASA Ames, told Discovery News. "The implication is that life may have an even easier time taking root, so to speak, in other parts of the galaxy."
The research will be published Sunday in The Astrophysical Journal.
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